Zirconia/carbon nanotube aerogel hybrid material: electrophysical and chemisorbtion properties

Authors

  • E.A. Tolmacheva Institute of Natural Sciences and Mathematics, Ural Federal University
  • I.A. Morozov Institute of Continuous Media Mechanics UB RAS; Perm State National Research University
  • A.G. Starostin Perm National Research Polytechnic University image/svg+xml

DOI:

Keywords:

zirconia, nanocarbon, chemisorption, electric conductivity

Abstract

The work is devoted to investigation of electrophysical properties of a zirconia/carbon nanotube composite and analysis of its sorption ability in relation to hydrogen. On the basis of conductive atomic-force microscopy, as well as the experiments performed on macroscopic scale it has been revealed that the material exhibits bulk percolation cluster-like conductivity. Besides, the synthesized material actively sorbs hydrogen in constant flow mode, as well as with a pulsed gas supply. The discovered properties of the composite make it of high demand in the field of catalysis, water vapor sensors and etc.

Author Biographies

  • E.A. Tolmacheva, Institute of Natural Sciences and Mathematics, Ural Federal University
    кандидат физико-математических наук, старший научный сотрудник
  • I.A. Morozov, Institute of Continuous Media Mechanics UB RAS; Perm State National Research University
    кандидат физико-математических наук, научный сотрудник лаборатории микромеханики структурно-неоднородных сред; инженер
  • A.G. Starostin, Perm National Research Polytechnic University
    кандидат технических наук, доцент

References

  1. Shearer C.J., Cherevan A., Eder D. // Adv. Mater. - 2014. - Vol. 26. - № 15. - P. 2295.
  2. Cherevan A.S., Gebhardt P., Shearer C.J., Matsukawa M., Domen K., Eder D. // Energy Environ. Sci. - 2014. - Vol. 7. - P. 791-796.
  3. Меньшутина Н.В., Каталевич А.М., Смирнова И. // Сверхкритические флюиды: теория и практика. - 2013. - Т. 8. - № 3. - С. 49-55.
  4. Pierre A.C., Pajonk G.M. Chemistry of aerogels and their applications // Chem. Rev. - 2002. - Vol. 102. - Р. 4243-4265.
  5. Aerogels handbook. Advances in sol-gel derived materials and technologies / Ed. M.A. Aegerter, M. Prassas. - Springer, 2011.
  6. Nardecchia S., Carriazo D., Ferrer M.L., Gutierrez M.C., del Monte F. // Chem. Soc. Rev. - 2013. - Vol. 42. - Р. 794-830.
  7. Ляпунова Е.А., Лунегов И.В., Уваров С.В., Наймарк О.Б. // Сб. тр. VIII Всерос. науч.-практ. совещания «Актуальные проблемы физики конденсированного состояния». - Екатеринбург: РИО УрО РАН, 2014. - С. 83-90.
  8. Lyapunova E.A., Uvarov S.V., Grigoriev M.V., Kulkov S.N., Naimark O.B. // Nanosystems: Phys. Chem. Math. - 2016. - Vol. 7(1). - P. 198-203. DOI 10.17586/22208054201671198203.
  9. Ляпунова Е.А., Морозов И.А., Наймарк О.Б. Электропроводность композита на основе аэрогеля оксид циркония/углеродные нанотрубки // Неорг. матер. - 2017. - Вып. 53. - № 2. - С. 170-174.

###

  1. Shearer C.J., Cherevan A., Eder D. // Adv. Mater. - 2014. - Vol. 26. - No 15. - P. 2295.
  2. Cherevan A.S., Gebhardt P., Shearer C.J., Matsukawa M., Domen K., Eder D. // Energy Environ. Sci. - 2014. - Vol. 7. - P. 791-796.
  3. Men’sutina N.V., Katalevic A.M., Smirnova I. // Sverhkriticeskie fluidy: teoria i praktika. - 2013. - T. 8. - No 3. - S. 49-55.
  4. Pierre A.C., Pajonk G.M. Chemistry of aerogels and their applications // Chem. Rev. - 2002. - Vol. 102. - R. 4243-4265.
  5. Aerogels handbook. Advances in sol-gel derived materials and technologies / Ed. M.A. Aegerter, M. Prassas. - Springer, 2011.
  6. Nardecchia S., Carriazo D., Ferrer M.L., Gutierrez M.C., del Monte F. // Chem. Soc. Rev. - 2013. - Vol. 42. - R. 794-830.
  7. Lapunova E.A., Lunegov I.V., Uvarov S.V., Najmark O.B. // Sb. tr. VIII Vseros. nauc.-prakt. sovesania <>. - Ekaterinburg: RIO UrO RAN, 2014. - S. 83-90.
  8. Lyapunova E.A., Uvarov S.V., Grigoriev M.V., Kulkov S.N., Naimark O.B. // Nanosystems: Phys. Chem. Math. - 2016. - Vol. 7(1). - P. 198-203. DOI 10.17586/22208054201671198203.
  9. Lapunova E.A., Morozov I.A., Najmark O.B. Elektroprovodnost’ kompozita na osnove aerogela oksid cirkonia/uglerodnye nanotrubki // Neorg. mater. - 2017. - Vyp. 53. - No 2. - S. 170-174.

Downloads

Published

2017-11-16

Issue

Section

Research: theory and experiment

How to Cite

Tolmacheva, E. ., Morozov, I. ., & Starostin, A. . (2017). Zirconia/carbon nanotube aerogel hybrid material: electrophysical and chemisorbtion properties. Perm Federal Research Centre Journal, 3, 74-79. https://journal-dev.icmm.ru/index.php/pscj/article/view/PSCJ2017n3p12